四色AV

A process for preparing compounds of formula: (II) by esterification of the C-17 hydroxyl group of 6伪, 9伪-difluoro-11尾, 17伪-dihydroxy-16伪-methyl-3-oxoandrosta-1,4-diene-17尾-carbothioic acid, the compound of formula: (I) comprises treating compound (I) with a slight excess of an acyl chloride of general formula R-COCI, where R represents -CH2CH3, -CH2CH2CH3 or -CH(CH3)2, in an inert solvent, in the presence of a tertiary amine. Preferably the process is carried out using pyridine in the presence of acetone at a temperature of from 5 掳C to -20 掳C. z.